• Home
    • About INSCI
    • Academic Portfolio
    • Management
    • Quality Systems
    • Policies
  • Programs
    • Language Studies
    • Corporate Training
    • Scientific Communications
    • Vocational Studies
    • Science Foundation studies
    • Formal Studies
  • Facilities
  • Business Projects
    • Sales and Marketing
    • Academic Projects
    • Bioscience
  • Contact
  • Employment

 

 
  SCIENCE FOUNDATION PROGRAM  
Handbook Contents
Introduction and Rationale
Learning Outcomes and Attendance
Admissions
Matriculation
 
Module Descriptions
Physics
Biology
Chemistry
Economics
Mathematics

 



CHEMISTRY


This module is designed for those students who are planning to gain admission into life science degree programmes offered at foreign tertiary institutions. The Chemistry module aims to equip students with a sound knowledge of the fundamental aspects of Chemistry to a level that is equivalent to GCE A level or HSC syllabus.

Module details

Language: English & Chinese
Lectures: 21 lectures (2 hours lecture)
Tutorials: 15 (1 hour/tutorial)
Practical assignments: 6 hours
Attendance: 12 hours per week
Assessments: Final exam 50%


Text

General Chemistry Interactive CD-ROM, Version 3.0 (Stand Alone), 3rd Edition William Vining, John C. Kotz and Patrick Harman
ISBN-10: 003035319X | ISBN-13: 9780030353192

 
       

 

   
       

Learning Outcomes

After studying this module you should have acquired the following knowledge and skills:Write down the names and symbols of more common elements together with an understanding of their properties, electron configuration and valency in relation to their position in the Periodic Table.

Show an understanding of the nature and variety of chemical bonds between atoms.

The ability to write down balanced chemical substances and concentrations both in units of weight and volume but also in molar form. Express the quantity of chemical substances and concentrations both in units of weight and volume but also in molar form.

Relate the structure of some simple organic compounds to their physical properties, such as boiling point, melting point and water solubility, using intermolecular Van der Waals forces and hydrogen bonding to explain.

Perform quantitative exercises in solubility, ionic equilibria and titrimetric analysis.

Define the nature of an acid, a base and a buffer solution. Define the terms acidity constant (Ka),pH pOH, pKw, pKa and pKb; calculate these values from provided data on acid/base ratios in the Henderson-Hasselbalch equation Sketch titration curves for weak acid and a weak base to show buffer regions, pKa and end-points. Understand radioisotopes their disintegration and release of energy.

The uses of radioisotopes in biomedical sciences research and medical diagnostic will also be discussed

The ability to relate the definition of oxidation and reduction to simple redox systems and write the appropriate half-reactions.

You should also have gained a thorough understanding of carbon chemistry and be able to identify the structures of important groups of organic compounds (alkanes, alkenes, alkynes, aromatic) and be conversant with the nomenclature of the major organic functional groups; structural and geometric isomers, molecular shapes.

In the last segment you will gain an understanding of the relative reactivity of a series of related compounds and the use of functional group transformations to change one molecule into another and the mechanisms that apply to these reactions.

             
        Lectures and Topics
       
Lecture  
1
States of Matter
• Derived Quantities and Scientific Notations and SI units
• The atom in physics and chemistry
• The periodic table and states of matter
• Definite particles of a matter and atomic mass
• Properties of gases, liquids and solids
• Boyles’s Law, Gay-Lussac’s Law; General and Ideal Gas Laws
• Avogardro’s Principle
• Dalton’s law of Partial Pressures
• Homogenous and heterogeneous mixtures (colloids)
• Physical and chemical changes
• States of matter: solids, liquids and gases
• Chemical Formulae
• The mole and Avogardro’s Law
• Calculation of moles, molarity, molality, normality, ppm, %, mole fractions and equivalents
• Osmosis and osmotic pressure
2
Atomic Theory and Electronic Structure
• Subatomic particles: Historical overview
• Atomic numbers, mass numbers and atomic weight
• Isotopes
• Bohr’s Planetary Model of the atom
• Heisenberg Uncertainty Principle
• Electron energy states - Energy levels/shells
• Quantum mechanics: Schrodinger Equation
• Electron orbitals and Pauli’s Exclusion Principle
• Aufbau Principle and Hund’s Rule
• Quantum mechanics and the Periodic Table
3

Electron Configurations and the Periodic Table
• Electron Orbitals
• Recap: Bohr: Electrons allowed energy states; Pauli Exclusion Principle.
• Aufbau Principle and Hund’s Rule
• Periodic Table: Periodicity, chemical family, valence electrons & Octet Rule
• Electronegativity, physical properties, atomic radius, first ionization energy, electron affinity,
• Electron configurations of cations and anions
• Elements for life

4
Chemical Bonds
• How atoms form molecules
• Types of chemical bond
• Ionization energies: Transferring and sharing of electrons
• Ionic bonds: Structure and formation compound
• Covalent bonds formation: Valence bond theory, Noble Gas configuration, Molecular orbits, Covalence number, Sigma and Pi bonds, Lewis structures and Valence electrons.
• Formation of polar covalent bonds (molecular polarity)
• Electron Sharing - hybrid orbitals
• Electron dot structures
• Polar versus non-polar covalent bonds
• Metallic and coordinate bonds
• Crystals
5
Electronegativity and Inductive Effects
• Bond formation and electronegativity
• Polar covalent bond formation
• Dipole moment and bonds
• Molecular polarity and inductive effects
• Resonance structures and effects
• Intermolecular forces: Dipole-dipole interactions; Hydrogen bonds; Van De Waals (London) forces.
• Intermolecular forces: Boiling points and Solubility
• Shape of molecules and VSEPR Theory
• Bond angles and dot structures
• Infrared Spectroscopy
6
Chemical Equations
• Writing balanced chemical equations
• Types of chemical equation will be discussed including: synthesis; decomposition; substitution; hydrolysis; combustion; neutralization; precipitation; hydrogenation; photosynthesis
• Stoichiometry and mass relationships
• Limiting reactions (reactants)
• Percentage yield
7
Energetics, Equilibrium and Kinetics
• Chemical equilibrium and the types of systems
• Reaction types: Exothermic and Endothermic reactions (Industrial applications)
• Le Chatelier’s principle
• Comparison between open & isolated systems
• Effect of Temperature, Pressure, Volume and Concentration
• Effect of catalyst
• Optimization of reaction rate
• Chemical equilibrium and Equilibrium Constant (Keq)
• Concentrations at equilibrium
• Industrial production of ammonia and sulfur trioxide
• Heterogeneous equilibrium
• Biochemical Reactions (glycogen synthesis, tooth decay, blood gas transport
• Enzyme catalysis
8
Reaction Rates
• Rates of reaction and factors affecting rates of reactions: Collision theory, activation energy,
• Catalyzed reactions
• Zero and Second Order reactions
• Reaction mechanism
• Rate laws of elementary reactions
• Rate determining step
9
Solubility and Partition
• Solubility rules
• Soluble and insoluble salts
• Writing precipitation reaction equations
• Heterogeneous equilibria and precipitation
• Solubility Product Constant and Ion Products
• Common ion effects
• Saturation and Molar solubilities
• Partition (distribution) coefficient and Fractions
• Biochemical extraction
• Partition: Acids and bases
• Industrial application of partition
• Calculation exercises
10
Ionic Equations
• Writing ionic formula
• Common ions
• Balancing and naming ionic compounds
• Ionic compounds containing: elements; and polyatomic ions
• Writing precipitation reactions (molecular, ionic, net ionic equations
• Formation of kidney stones
11
Acids and Bases
• Definitions and common acids and bases
• Bronsted-Lowry Acids and Bases
• Lewis acids
• pH and calculation of
• pH: Concentration of H and OH
• Ionization, dissociation and ion product of water, Kw
• Conjugate acid and base pairs
• Acid-base equilibria
• pH, strong acid and strong bases
• Organic compounds that are acids and bases (Resonance structures)
• Common Acid-Base Indicators
• Acid- Base Properties of Salts
• Salts that produce neutral, basic and acidic solutions
• Calculations
12
Chemical Analysis and Titrations
• Chemical analysis and titrations
• Indicators
• Titrations: Primary (1o) and Secondary standards
• Chemical equilibrium and Equilibrium Constant (Keq)
• Concentrations at equilibrium
• Titrations involving: strong and weak acids and bases
• Ka & Kb (Relationship), pH, pOH, pKw, pKa and pKb
• Buffer solutions
• Henderson-Hasselbach Equation: derivation
• Weak acid (Ka) and weak base (Kb) ionization Constants)
• Calculations of acid-base reactions
13
Gas Laws, Phases & Chemical Potentials
• Daltons law
• Partial pressure of gases and mole fraction
• Ideal gases
• Avogardro’s Law and molar volume
• Boyles Law, Charles Law
• Gas laws and Ideal Gas Equation
• Phase diagram
• Freeze drying and distillation
• Real gases and effect of departures from ideality
• Homogenous and heterogeneous equilibria
• Phase rule
• Extensive and intensive (colligative) properties:
• Evaporation and vapour pressure
• Raoult’s Law
• Chemical potential, diffusion and stoichiometry
14
Oxidation and Reduction
• Oxidation and reduction agents: Redox reactions
• Oxidation number rules and balancing redox equations
• Electrode potentials: Standard hydrogen electrode
• Standard electrode and redox potentials
• Standard Cell Potential Ecell
• Reaction Prediction from standard cell potentials
• Electrolysis, F=L?
• Oxidation and Reduction - Life Science
• Respiration and anaerobic respiration
• Splitting redox reactions and standardized half-reactions
• Free energy and standard reduction
• Redox and non standard conditions
15
Thermodynamics
• Introduction: Count Rumford, Joule, etc.
• First law of thermodynamics
• Internal energy (Potential and Kinetic Energy)
• Heat calculations and specific heat capacities
• Activation energy
• Enthalpy, Enthalpy of formation and dissociations with calculations
• Hess’s Law
• Second Law of Thermodynamics: Entropy
• Gibbs Free Energy
• Reaction isotherm equation
• Van’t Hoff Equation (Reaction Isochore)
16
Isotopes Radioactivity
• Radioactivity and nuclear definitions
• Transformation Series
• Radioactive Isotopes and their half-life
• Nuclear equations for alpha, beta and gamma radiation
• Balancing nuclear reactions and decay series
• Nuclear Fission and energy of nuclear fission
• Transmutation and fission
• Separation of isotopes
• Ionizing radiation and nuclear energy
• Free radicals and the effects of radiation
• Nuclear fusion, mass defect and energy
• Nuclear bombs and the scientists
• Fundamental particles of matter
• Effects of radiation and protection
• Inverse square law and background radiation
• Units of radiation and older units of radiation
• Absorbed Dose and dose equivalent
• Energy of gamma- or X-rays and
• Measuring of ionizing radiation
• Radiation in the food industry and life sciences
• Biological application – advantages and disadvantages
• Medical Diagnosis and Therapy: Radionuclides usage.
• Types of Radiation Therapy
• CT Scanner, MRI scan and PET-scan
17
Review of Structure and Bonding
• Bonds: Covalent (single and multiple)
• Lewis dot structure and determination of charge
• Exceptions to octet rule
• Electron pushing
• Resonance contributors
• Shapes of molecules (VSEPR)
• Polarity of organic molecules
• Valence bond (hybridization and molecular orbital theory)
• Reaction mechanisms
18
Organic chemistry
• Nomenclature (IUPAC)
• Hydrocarbons (saturated and unsaturated): Alkanes, alkenes and Alkynes
• Non-halogenated and halogenated
• Organic compounds: Formulae and naming
• Functional groups, properties and chemical reactions of: alcohols; aldehydes; ketones; carboxylic acids; ethers; esters; organo-phosphate esters; amines; amides; thiols (mercaptans); and aromatic compounds.
• Standard organic reactions: Homolytic and Heterolytic fission, Nucleophilic and Electrophilic reactions, Free-radical substitution, electrophilic addition and substitution, nucleophilic substitution and addition reactions; oxidation; reduction; and hydrolysis
19
Hydrocarbons
• Properties of alkanes and alkenes
• Covalent bond fission (hemolytic and heterolytic fission)
• Carbonium ion structure and properties
• Nucleophilic substitution and elimination reactions
• Nomenclature of alkanes, alkenes and cyclic hydrocarbons
• Alkanes and cycloalkanes
• Alkyl-groups
• Groups of organic compounds
• Reactions of the alkanes – oxidation and halogenation
• Unsaturated alkanes: Alkenes and Bonding
• Reactions of Alkenes
• Cycloalkanes and cycloalkenes
• Generation of racemate mixtures
• SN1 and SN2, E1 and E2 mechanisms
• Hydrogenation and halogenation reactions
20
Isomers
• Stereochemistry: Structural isomerism (skeletal, functional and positional)
• Geometrical isomers: Cis and trans isomers
• Conformation isomers and Newman projection (boat and chair isomers)
• Optical isomers: Enantiomers: Properties of Enantiomers
• Nomenclature: The sequence rule
• Fischer projection (S and R forms)
• Molecules with two chiral centres (diastereomers)
• Physical properties of isomers
• Exercises
21
Reaction Mechanisms
• SN1 and SN2
• Effects of solvents
• Nucleophiles and electrophiles
• Elimination reactions (E1 and E2)
• Saytzev’s rule
• Predicting preferred pathways

Education

  • Portfolio
  • Academic business
  • Vocational Studies
  • Degree Programs
  • Study on the South Coast

Consulting

  • Chemical process
  • Complementary Medicines
  • Pharmaceuticals
  • Quality Systems
  • Marketing

Contact Us

  • +61 (0) 434577580
  • info@insci.com.au
© 2023~2028 INSCI - All Rights Reserved design by HowV